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Synthesis 2018; 50(03): 593-598
DOI: 10.1055/s-0036-1591515
DOI: 10.1055/s-0036-1591515
paper
Glycosylation of Stannyl Ceramides Promoted by Modified Montmorillonite in Supercritical Carbon Dioxide
Authors
The authors are very grateful for the economic support acquired from CONACyT (Institutional Links FONCICYT-275694), FERMIC S. A. de C.V. and PRODEP-SEP (DSA/103.5/16/10288). J.A.M.S. and B.N.N. acknowledge support from the Royal Society, British Council, Newton Fund and Newton Fellowship Alumni Program.
Further Information
Publication History
Received: 12 August 2017
Accepted after revision: 06 October 2017
Publication Date:
07 November 2017 (online)
Abstract
The direct glycosylation of ceramides in supercritical carbon dioxide (scCO2) successfully proceeded to produce β-glycolipids in high yield and with full stereoselectivity. The reaction is promoted by montmorillonite modified with a superacid (CF3SO3H). The value of this protocol was demonstrated in the efficient synthesis of isoglobotrihexosylceramide (iGB3).
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1591515.
- Supporting Information (PDF)
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